MATERIAL SAFETY DATA SHEET

 

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SECTION 1 - MATERIAL IDENTIFICATION

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PRODUCT NAMES

 

EP5330 - Hardener

EP5340 - Hardener

EP5341 Hardener

EP5342 Hardener

EP5356 Hardener

EP7344 Hardener

EP7346 Hardener

EP7348 Hardener

EP7350 Hardener

EP7356 Hardener

EP0942 Hardener

EP92-0630 Hardener

EP85-215 Hardener

 

MSDS REVISION NUMBER 8

 

 

FROM

Eager Polymers

3350 W. 48th Place

Chicago, IL 60632

Back to our homepage at: www.eagerpolymers.com

 

TELEPHONE NUMBER 773-927-3484

 

REVISION DATE November 2009

 

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EMERGENCY OVERVIEW

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HMIS/NFPA HEALTH 2 FLAMMABILITY 1 REACTIVITY 0

 

PHYSICAL FORM Mobile liquid

 

COLOR Amber

 

ODOR Fishy

 

HAZARDS Mild skin irritant. May cause skin sensitization.

 

EXTINGUISHING MEDIA Ignition will give rise to a Class B fire. In

case of large fire use: alcohol foam, water

spray. In case of small fire use: carbon dioxide

(CO2), dry chemical, dry sand or limestone.

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C.A.S. CHEMICAL NAME Mixture

 

SYNONYMS None

 

CHEMICAL FAMILY Aliphatic Amines

 

EMPIRICAL FORMULA Mixture

 

INTENDED USE Curing Agent, Epoxy

 

REVISION NOTES Updated Reactivity Information.

 

 

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SECTION 2 - INGREDIENTS

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Num % CAS Number and Chemical Name

--- ------- ---------------------------------------------------------

1. >75.00 26950-63-0 TETA, REACTION PRODUCTS WITH PROPYLENE OXIDE

2. <25.00 112-24-3 TRIETHYLENETETRAMINE (TETA)

 

OSHA (ACGIH) EXPOSURE LIMITS

TWA STEL CEILING

ppm mg/m3 ppm mg/m3 ppm mg/m3

-------- -------- -------- -------- -------- --------

1. OSHA N/E N/E N/E N/E N/E N/E

ACGIH N/E N/E N/E N/E N/E N/E

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2. OSHA N/E N/E N/E N/E N/E N/E

ACGIH N/E N/E N/E N/E N/E N/E

 

N/E = Not Established.

 

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SECTION 3 - HEALTH HAZARDS

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ROUTES OF EXPOSURE

Eye Contact

Skin Contact

Ingestion

Skin Absorption

 

EXPOSURE STANDARDS

No standards established for the product. Maintain air contaminant

concentrations in the workplace at the lowest feasible levels.

 

HEALTH HAZARDS

Mild skin irritant.

May cause skin sensitization.

 

TARGET ORGANS

Eye

Skin

 

SIGNS AND SYMPTOMS OF EXPOSURE (Acute effects)

Product vapor in low concentrations can cause lacrimation,

conjunctivitis and corneal edema when absorbed into the tissue of

the eye from the atmosphere. Corneal edema may give rise to a

perception of ''blue haze'' or ''fog'' around lights. The effect

is transient and has no known residual effect. Contact with skin

causes mild irritation and discomfort. Inhalation of mists may

cause irritation in the respiratory tract.

Product is absorbed through the skin and may cause nausea,

headache and general discomfort.

 

SIGNS AND SYMPTOMS OF EXPOSURE (Possible Longer Term Effects)

Repeated and/or prolonged exposure may cause allergic

reaction/sensitization.

Repeated and/or prolonged exposures may result in: adverse eye

effects (such as conjunctivitis or corneal damage), adverse skin

effects (such as rash, irritation or corrosion).

 

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE

Eye disease

Skin disorders and Allergies

 

CARCINOGENS UNDER OSHA, ACGIH, NTP, IARC, OTHER

This product contains no carcinogens in concentrations of 0.1

percent or greater.

 

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SECTION 4 - FIRST AID

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EYE CONTACT

Rinse immediately with plenty of water.

 

SKIN CONTACT

Wash affected area with soap and water. Remove contaminated

clothing and shoes. Destroy contaminated leather apparel. Launder

contaminated clothing prior to reuse.

 

INHALATION

Move patient to fresh air. If breathing has stopped or is labored

give assisted respiration (e.g. mouth-to-mouth). Supplemental

oxygen may be indicated. Prevent aspiration of vomit. Turn

victim's head to the side. Seek medical advice.

 

INGESTION

If swallowed, call a physician immediately. Remove stomach

contents by gastric suction or induce vomiting only as directed by

medical personnel. Never give anything by mouth to an unconscious

person.

 

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SECTION 5 - FIRE AND EXPLOSION DATA

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FLASH POINT (closed cup) 175.00 C (347.00 F)

 

UPPER EXPLOSION LIMIT (UEL) No Data

LOWER EXPLOSION LIMIT (LEL) No Data

 

AUTOIGNITION TEMPERATURE No Data

FIRE HAZARD CLASSIFICATION (OSHA/NFPA)

Class IIIB

 

EXTINGUISHING MEDIA

Ignition will give rise to a Class B fire. In case of large fire

use: water spray, alcohol foam. In case of small fire use: carbon

dioxide (CO2), dry chemical, dry sand or limestone.

 

SPECIAL FIRE FIGHTING PROCEDURES

Firefighters should wear butyl rubber boots, gloves, and body suit

and a self-contained breathing apparatus.

 

UNUSUAL FIRE AND EXPLOSION HAZARDS

May generate toxic or irritating combustion products.

Sudden reaction and fire may result if product is mixed with an

oxidizing agent.

May generate carbon monoxide gas.

May generate toxic nitrogen oxide gases. May generate ammonia gas.

Personnel in vicinity and downwind should be evacuated.

 

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SECTION 6 - ACCIDENTAL RELEASE MEASURES

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CONTAINMENT TECHNIQUES (Removal of ignition sources, diking etc)

Stop the leak, if possible. Reduce vapor spreading with a water

spray. Shut off or remove all ignition sources. Construct a dike

to prevent spreading (includes molten liquids until they freeze).

 

CLEAN-UP PROCEDURES

If recovery is not feasible, admix with dry soil, sand or non-

reactive absorbent and place in an appropriate chemical waste

container. Transfer to containers by suction, preparatory for

later disposal. Place in metal containers for recovery or

disposal. Flush area with water spray. Clean-up personnel must be

equipped with self contained breathing apparatus and butyl rubber

protective clothing. For large spills, recover spilled material

with a vacuum truck.

 

OTHER EMERGENCY ADVICE

Wear protective clothing, boots, gloves, and eye protection. At

elevated temperatures a cartridge mask National Institute for

Occupational Safety and Health (NIOSH) approved for ammonia may be

appropriate.

 

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SECTION 7 - HANDLING AND STORAGE

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STORAGE

Keep away from: acids, oxidizers. Keep in cool, dry, ventilated

storage and in closed containers. Do not store in reactive metal

containers.

 

HANDLING

Avoid contact with skin or eyes. When handling, do not eat, drink,

or smoke.

 

OTHER PRECAUTIONS

Emergency showers and eye wash stations should be readily

accessible. Adhere to work practice rules established by

government regulations (e.g. OSHA). Do not use sodium nitrite or

other nitrosating agents in formulations containing this product.

Cancer-causing nitrosamines could be formed.

 

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SECTION 8 - PERSONAL PROTECTION / EXPOSURE CONTROLS

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EYE PROTECTION

Chemical safety glasses.

 

HAND PROTECTION

Neoprene rubber gloves. Cuffed butyl rubber gloves. Nitrile rubber

gloves.

 

RESPIRATORY PROTECTION

Not required under normal conditions in a well-ventilated

workplace. At elevated temperatures a cartridge mask National

Institute for Occupational Safety and Health (NIOSH) approved for

ammonia may be appropriate.

 

PROTECTIVE CLOTHING

Long sleeved clothing.

 

ENGINEERING CONTROLS

No specific controls needed.

 

WORK AND HYGIENIC PRACTICES

Provide readily accessible eye wash stations and safety showers.

Wash at the end of each workshift and before eating, smoking or

using the toilet. Discard contaminated leather articles.

 

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SECTION 9 - TYPICAL PHYSICAL AND CHEMICAL PROPERTIES

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PHYSICAL FORM Mobile liquid

COLOR Amber

ODOR Fishy

pH No Data

VAPOR PRESSURE (mm Hg at 21C (70F)) <1.00000

VAPOR DENSITY (Air = 1) No Data

BOILING POINT >200.00 C (>392.00 F)

MELTING POINT No Data

SOLUBILITY IN WATER Slight (0.1 - 1%)

SPECIFIC GRAVITY (Water = 1) 1.02

MOLECULAR WEIGHT Mixture

 

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SECTION 10 - STABILITY AND REACTIVITY

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CHEMICAL STABILITY

Stable

 

CONDITIONS TO AVOID (if unstable)

Not applicable

 

INCOMPATIBILITY (Materials to Avoid)

Mineral acids (i.e. sulfuric, phosphoric, etc.). Organic acids

(i.e. acetic acid, citric acid etc.). Oxidizing Agents (i.e.

perchlorates, nitrates etc.). Sodium or Calcium Hypochlorite.

CAUTION! N-Nitrosamines, many of which are known to be potent

carcinogens, may be formed when the product comes in contact with

nitrous acid, nitrites or atmospheres with high nitrous oxide

concentrations. Product slowly corrodes copper, aluminum, zinc and

galvanized surfaces. Reaction with peroxides may result in violent

decomposition of peroxide possibly creating an explosion.

Nitrites, nitrosating agents. A reaction accompanied by large heat

release occurs when the product is mixed with acids. Heat

generated may be sufficient to cause vigorous boiling creating a

hazard due to splashing or splattering of hot material.

 

HAZARDOUS DECOMPOSITION PRODUCTS (from burning, heating, or reaction

with other materials).

Nitrogen oxide can react with water vapors to form corrosive

nitric acid (TLV=2 ppm). Carbon Monoxide in a fire. Carbon Dioxide

in a fire. Ammonia when heated. Nitrogen Oxides in a fire.

Irritating and toxic fumes at elevated temperatures. Nitric acid

in a fire. nitrosamines. The oxides of nitrogen gases (except

nitrous oxide) emitted on decomposition are highly toxic.

 

HAZARDOUS POLYMERIZATION

Will not occur

 

CONDITIONS TO AVOID (if polymerization may occur)

Not applicable

 

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SECTION 11 - TOXICOLOGICAL PROPERTIES

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ACUTE ORAL TOXICITY (LD50, RAT)

>2000.00 mg/kg (No deaths) (Estimate)

 

ACUTE DERMAL TOXICITY (LD50, RABBIT)

>2000.00 mg/kg (Estimate)

 

ACUTE INHALATION TOXICITY (LC50, RAT)

No Data

 

OTHER DATA

Toxicity data from similar products.

 

OTHER ACUTE EFFECTS

No Data

 

IRRITATION EFFECTS DATA

Mild irritant to the skin of a rabbit.

 

CHRONIC/SUBCHRONIC DATA

No delayed, subchronic or chronic test data are known.

 

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SECTION 12 - ECOLOGICAL INFORMATION

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ECOTOXICITY

No Data

ENVIRONMENTAL FATE

No Data

ADDITIONAL INFORMATION

Waste from this product may present long term environmental

hazards, thus landfill disposal must be considered less acceptable

than incineration..

 

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SECTION 13 - DISPOSAL CONSIDERATIONS

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WASTE DISPOSAL

Comply with all Federal, State and Local Regulations.

 

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SECTION 14 - TRANSPORT INFORMATION

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DOT NON-BULK SHIPPING NAME RESIN COMPOUND - Not DOT Regulated

 

DOT BULK SHIPPING NAME Refer to Bill of Lading.

IMO SHIPPING DATA Refer to Bill of Lading.

 

ICAO/IATA SHIPPING DATA RESIN COMPOUND - Not IATA Regulated

 

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SECTION 15 - REGULATORY INFORMATION

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US FEDERAL REGULATIONS

 

TOXIC SUBSTANCES CONTROL ACT (TSCA)-

All components are included in the EPA Toxic Substances Control

Act (TSCA) Chemical Substance Inventory.

 

OSHA Hazard Communication Standard (29CFR1910.1200) hazard class(es)

Sensitizer.

 

EPA SARA Title III Section 312 (40CFR370) hazard class

Delayed Health Hazard.

 

EPA SARA Title III Section 313 (40CFR372) toxic chemicals above "de

minimis" level are

None

 

STATE REGULATIONS

 

PROPOSITION 65 SUBSTANCES (component(s) known to the State of

California to cause cancer and/or reproductive toxicity and subject

to warning and discharge requirements under the "Safe Drinking Water

and Toxic Enforcement Act of 1986")

None

 

NEW JERSEY TRADE SECRET REGISTRY NUMBER(S)

None

 

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SECTION 16 - INTERNATIONAL REGULATIONS

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CANADA

DSL

Included on Inventory.

WHMIS HAZARD CLASSIFICATION

Class D Division 2B,

WHMIS TRADE SECRET REGISTRY NUMBER(S)

None

WHMIS HAZARDOUS INGREDIENTS

TRIETHYLENETETRAMINE (TETA)

WHMIS SYMBOLS

Stylized T,

 

EUROPEAN ECONOMIC COMMUNITY (EEC)

EINECS/ELINCS MASTER INVENTORY

Included on EINECS inventory or polymer substance, monomers

included on EINECS inventory or no longer polymer.

EEC SYMBOL

IRRITANT (Xi)

EEC RISK (R) PHRASES

May cause sensitization by skin contact (R43). Irritating

to eyes (R36).

EEC SAFETY PHRASES

In case of contact with eyes, rinse immediately with plenty

of water and seek medical advice (S26). Wear suitable

protective clothing and gloves (S36/37).

AUSTRALIA

AICS

Included on Inventory.

JAPAN MITI

Not on Inventory.

PHILIPPINES PICCS

Not on Inventory.

KOREA ECL

Included on Inventory.

CHINA SEPA

Not on Inventory.

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END OF DOCUMENT